1. Identification
Product Name 4-Piperidone ethylene ketal
Cat No. : 14PE
Synonyms 4-Piperidone ethylene ketal
Recommended Use Laboratory chemicals.
Uses advised against No Information available
Details of the supplier of the safety data sheet
2. Hazard(s) identification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Signal Word
Hazard Statements
Combustible liquid
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
Nile Chemicals
Masjid Bunder
Tel: 91-022-66313162
Skin Corrosion/irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.
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Flammable liquids Category 4
Precautionary Statements
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep cool
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
In case of fire: Use CO2, dry chemical, or foam for extinction
Store in a well-ventilated place. Keep container tightly closed
Store locked up
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
3. Composition / information on ingredients
Component CAS-No Weight %
1,4-Dioxa-8-azaspiro[4.5]decane 177-11-7 98
4. First-aid measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes.
Inhalation Remove from exposure, lie down. Move to fresh air.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Drink
plenty of water. If possible drink milk afterwards.
Most important symptoms/effects Breathing difficulties. Symptoms of overexposure may be headache, dizziness, tiredness,
nausea and vomiting
Notes to Physician Treat symptomatically
5. Fire-fighting measures
Suitable Extinguishing Media Water spray. Carbon dioxide (CO 2). Dry chemical. alcohol-resistant foam.
Unsuitable Extinguishing Media
No information available
Flash Point
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81 C / 177.8 F
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition.
Hazardous Combustion Products
Nitrogen oxides (NOx) Thermal decomposition can lead to release of irritating gases and vapors Carbon monoxide (CO) Carbon
dioxide (CO2)
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
6. Accidental release measures
Personal Precautions Ensure adequate ventilation. Use personal protective equipment.
Environmental Precautions See Section 12 for additional ecological information.
Methods for Containment and Clean
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust). Keep in suitable, closed containers for disposal. Sweep up or vacuum up spillage
and collect in suitable container for disposal.
7. Handling and storage
Handling Avoid contact with skin and eyes. Avoid contact with clothing. Remove and wash
contaminated clothing before re-use. Avoid breathing vapors or mists. Do not ingest. Wash
thoroughly after handling.
Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed.
8. Exposure controls / personal protection
Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits
established by the region specific regulatory bodies.
Physical hazards
Engineering Measures Ensure adequate ventilation, especially in confined areas. Ventilation systems.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline
respirator in the positive pressure mode with emergency escape provisions.
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Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
9. Physical and chemical properties
Physical State Liquid
Appearance Light yellow
Odor Odorless
Odor Threshold No information available
pH No information available
Melting Point/Range No data available
Boiling Point/Range 108 - 110 C / 226.4 - 230 F @ 26 mmHg
Flash Point 81 C / 177.8 F
Evaporation Rate No information available
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density 4.94
Relative Density 1.110
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity No information available
Molecular Formula C7 H13 N O2
Molecular Weight 143.19
10. Stability and reactivity
Reactive Hazard None known, based on information available
Stability Stable under normal conditions.
Conditions to Avoid Incompatible products.
Incompatible Materials Strong oxidizing agents
Hazardous Decomposition Products Nitrogen oxides (NOx), Thermal decomposition can lead to release of irritating gases and
vapors, Carbon monoxide (CO), Carbon dioxide (CO2)
Hazardous Polymerization No information available.
Hazardous Reactions None under normal processing.
11. Toxicological information
Acute Toxicity
Product Information No acute toxicity information is available for this product
Component Information
Toxicologically Synergistic
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
1,4-Dioxa-8-azaspiro[4 177-11-7 Not listed
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Not listed Not listed Not listed Not listed
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.
12. Ecological information
Do not empty into drains.
Persistence and Degradability No information available
Bioaccumulation/ Accumulation No information available.
Mobility No information available.
13. Disposal considerations
Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
14. Transport information
DOT Not regulated
TDG Not regulated
IATA Not regulated
IMDG/IMO Not regulated
15. Regulatory information
International Inventories
- - - 205-868-6 - - - - - -
X - Listed
E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated
polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
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S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base
Production and Site Reports (40 CFR 710(B).
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants
that comprises one of the eligibility criteria for the exemption rule.
U.S. Federal Regulations
TSCA 12(b) Not applicable
SARA 313 Not applicable
SARA 311/312 Hazardous Categorization
Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Clean Water Act Not applicable
Clean Air Act Not applicable
OSHA Occupational Safety and Health Administration
Not applicable
Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals
State Right-to-Know Not applicable
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR
WHMIS Hazard Class
B3 Combustible liquid
D2B Toxic materials
16. Other information
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The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.


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