SAFETY DATA SHEET 1. Identification Product Name 4-Piperidone ethylene ketal Cat No. : 14PE Synonyms 4-Piperidone ethylene ketal Recommended Use Laboratory chemicals. Uses advised against No Information available Details of the supplier of the safety data sheet 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Warning Hazard Statements Combustible liquid Causes skin irritation Causes serious eye irritation May cause respiratory irritation Company Nile Chemicals Masjid Bunder MUMBAI 400009 INDIA Tel: 91-022-66313162 Skin Corrosion/irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Specific target organ toxicity (single exposure) Category 3 ______________________________________________________________________________________________ Target Organs - Respiratory system. Page 1 / 7 Flammable liquids Category 4 ______________________________________________________________________________________________ 1,4-Dioxa-8-azaspiro[4.5]decane Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep cool Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Skin IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition / information on ingredients Component CAS-No Weight % 1,4-Dioxa-8-azaspiro[4.5]decane 177-11-7 98 4. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Inhalation Remove from exposure, lie down. Move to fresh air. Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. If possible drink milk afterwards. Most important symptoms/effects Breathing difficulties. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Notes to Physician Treat symptomatically 5. Fire-fighting measures Suitable Extinguishing Media Water spray. Carbon dioxide (CO 2). Dry chemical. alcohol-resistant foam. Unsuitable Extinguishing Media ______________________________________________________________________________________________ No information available Flash Point Page 2 / 7 81 °C / 177.8 °F Method - No information available ______________________________________________________________________________________________ 1,4-Dioxa-8-azaspiro[4.5]decane Autoignition Temperature No information available Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx) Thermal decomposition can lead to release of irritating gases and vapors Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. NFPA 6. Accidental release measures Personal Precautions Ensure adequate ventilation. Use personal protective equipment. Environmental Precautions See Section 12 for additional ecological information. Methods for Containment and Clean Up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Sweep up or vacuum up spillage and collect in suitable container for disposal. 7. Handling and storage Handling Avoid contact with skin and eyes. Avoid contact with clothing. Remove and wash contaminated clothing before re-use. Avoid breathing vapors or mists. Do not ingest. Wash thoroughly after handling. Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed. 8. Exposure controls / personal protection Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Health 2 Flammability 1 Instability 0 Physical hazards N/A Engineering Measures Ensure adequate ventilation, especially in confined areas. Ventilation systems. Personal Protective Equipment Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. ______________________________________________________________________________________________ Respiratory Protection Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Page 3 / 7 Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. ______________________________________________________________________________________________ 1,4-Dioxa-8-azaspiro[4.5]decane 9. Physical and chemical properties Physical State Liquid Appearance Light yellow Odor Odorless Odor Threshold No information available pH No information available Melting Point/Range No data available Boiling Point/Range 108 - 110 °C / 226.4 - 230 °F @ 26 mmHg Flash Point 81 °C / 177.8 °F Evaporation Rate No information available Flammability (solid,gas) No information available Flammability or explosive limits Upper No data available Lower No data available Vapor Pressure No information available Vapor Density 4.94 Relative Density 1.110 Solubility No information available Partition coefficient; n-octanol/water No data available Autoignition Temperature No information available Decomposition Temperature No information available Viscosity No information available Molecular Formula C7 H13 N O2 Molecular Weight 143.19 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. Conditions to Avoid Incompatible products. Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Nitrogen oxides (NOx), Thermal decomposition can lead to release of irritating gases and vapors, Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization No information available. Hazardous Reactions None under normal processing. 11. Toxicological information Acute Toxicity Product Information No acute toxicity information is available for this product Component Information Toxicologically Synergistic Products No information available Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation No information available Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA ______________________________________________________________________________________________ Mexico 1,4-Dioxa-8-azaspiro[4 177-11-7 Not listed Page 4 / 7 Not listed Not listed Not listed Not listed ______________________________________________________________________________________________ 1,4-Dioxa-8-azaspiro[4.5]decane .5]decane Mutagenic Effects No information available Reproductive Effects No information available. Developmental Effects No information available. Teratogenicity No information available. STOT - single exposure Respiratory system STOT - repeated exposure None known Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor Information No information available Other Adverse Effects The toxicological properties have not been fully investigated. 12. Ecological information Ecotoxicity Do not empty into drains. Persistence and Degradability No information available Bioaccumulation/ Accumulation No information available. Mobility No information available. 13. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT Not regulated TDG Not regulated IATA Not regulated IMDG/IMO Not regulated 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL 1,4-Dioxa-8-azaspiro[4.5]dec ane - - - 205-868-6 - - - - - - Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. ______________________________________________________________________________________________ F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. Page 5 / 7 S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. ______________________________________________________________________________________________ 1,4-Dioxa-8-azaspiro[4.5]decane Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) Not applicable SARA 313 Not applicable SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Not applicable Clean Air Act Not applicable OSHA Occupational Safety and Health Administration Not applicable CERCLA Not applicable California Proposition 65 This product does not contain any Proposition 65 chemicals State Right-to-Know Not applicable U.S. Department of Transportation Reportable Quantity (RQ): N DOT Marine Pollutant N DOT Severe Marine Pollutant N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade No information available Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class ______________________________________________________________________________________________ B3 Combustible liquid D2B Toxic materials 16. Other information Page 6 / 7 ______________________________________________________________________________________________ ______________________________________________________________________________________________ Page 7 / 7 Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
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