NILE CHEMICALS                            

SILVER NITRATE


1. Product Identification

Synonyms: Lunar caustic; silver nitrate toughened; Nitric Acid, Silver (I) Salt
CAS No.: 7761-88-8
Molecular Weight: 169.87
Chemical Formula: AgNO3
Product Codes:  N7901


2. Composition/Information on Ingredients

 

  Ingredient                                CAS No         Percent        Hazardous                                  
  ---------------------------------------   ------------   ------------   ---------   
 
  Silver Nitrate                            7761-88-8        99 - 100%       Yes                                                                    
 

3. Hazards Identification


Health Rating: 3 - Severe (Poison)
Flammability Rating: 0 - None
Reactivity Rating: 3 - Severe (Oxidizer)
Contact Rating: 3 - Severe (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: Yellow (Reactive)
-----------------------------------------------------------------------------------------------------------

Potential Health Effects
----------------------------------

Inhalation: Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. May be absorbed into the body following inhalation with symptoms paralleling those from ingestion exposure. Dust deposits in the lungs may resemble a form of pneumoconiosis.
Ingestion: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach. Can cause sore throat, vomiting, diarrhea. Poison. Symptoms include pain and burning in the mouth, blackening of the skin and mucous membranes, throat, and abdomen, salivation, vomiting of black material, diarrhea, collapse, shock, coma and death.
Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur.
Eye Contact: Corrosive. Can cause blurred vision, redness, pain, severe tissue burns and eye damage.
Chronic Exposure: Repeated application or ingestion causes a permanent bluish discoloration of the skin, conjunctiva, and mucous membranes. Repeated inhalation may cause lung disease.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of the substance.


4. First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.


5. Fire Fighting Measures

Fire: This oxidizing material can increase the flammability of adjacent combustible materials.
Explosion: Many reactions may cause explosion. Reacts with ammonia to form compounds that are sensitive to mechanical shock.
Fire Extinguishing Media: Use flooding amounts of water. Do not use dry chemical, carbon dioxide or Halon. Do not allow water runoff to enter sewers or waterways.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.


6. Accidental Release Measures

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

 


7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Protect from light. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.


8. Exposure Controls/Personal Protection

Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):
0.01 mg/m3 (TWA) for silver metal dust and fume as Ag

-ACGIH Threshold Limit Value (TLV):
0.01 mg /m3 (TWA) for soluble silver compounds as Ag
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids. glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.


9. Physical and Chemical Properties

Appearance: Transparent, colorless crystals.
Odor: Odorless.
Solubility: 219g/100g water @ 20C (68F).
Specific Gravity: 4.352
pH: ca. 6 (neutral to litmus)
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 444C (831F) Decomposes.
Melting Point: 212C (414F)
Vapor Density (Air=1): 4.4
Vapor Pressure (mm Hg): Very low.
Evaporation Rate (BuAc=1): No information found.


10. Stability and Reactivity

Stability: Stable at room temperature in sealed containers. Discolors on exposure to light.
Hazardous Decomposition Products: Oxides of nitrogen.
Hazardous Polymerization: Will not occur.
Incompatibilities: Ammonia, alkalis, antimony salts, arsenites, bromides, carbonates, chlorides, iodides, thiocyanates, ferrous salts, phosphates, tannic acid and tartrates.
Conditions to Avoid: Heat, flame, sources of ignition, light and incompatibles.


11. Toxicological Information


Oral rat LD50: 1173 mg/kg. Irritation data, rabbit, std Draize: eye= 1 mg, severe. Investigated as a tumorigen, mutagen, reproductive effector.

  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Silver Nitrate (7761-88-8)              No          No            None

12. Ecological Information

Environmental Fate: No information found.
Environmental Toxicity: No information found.


13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.


14. Transport Information

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: RQ, SILVER NITRATE
Hazard Class: 5.1
UN/NA: UN1493
Packing Group: II
Information reported for product/size: 500G

International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: SILVER NITRATE
Hazard Class: 5.1
UN/NA: UN1493
Packing Group: II
Information reported for product/size: 500G


15. Regulatory Information

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Silver Nitrate (7761-88-8)                        Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Silver Nitrate (7761-88-8)                        Yes   Yes   No     Yes       
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Silver Nitrate (7761-88-8)                 No    No      No    Sliver cmpd/
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Silver Nitrate (7761-88-8)                 1          No         No     
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: Yes         (Pure / Solid)  

16. Other Information

Nile Chemicals provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. NILE CHEMICALS MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE CHEMICALS WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.

 

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