NILE CHEMICALS

Material Safety Data Sheet

Tin(II) sulfate

 

Section 1 - Chemical Product and Company Identification

MSDS Name: Tin(II) sulfate
Synonyms: Stannous sulfate.
Company Identification:
              Nile Chemicals

Section 2 - Composition, Information on Ingredients

 

CAS#

Chemical Name

Percent

EINECS/ELINCS

 

 

7488-55-3

Tin(II) sulfate

95

231-302-2

 

Section 3 - Hazards Identification

         



Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation: Causes respiratory tract irritation. May be harmful if inhaled.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Chronic exposure to tin oxide dusts and fumes may result in stannosis (benign pneumoconiosis).

Section 4 - First Aid Measures



Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures



General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 1

Section 6 - Accidental Release Measures



General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment.

Section 7 - Handling and Storage



Handling: Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage: Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection



Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name

ACGIH

NIOSH

OSHA - Final PELs

Tin(II) sulfate

2 mg/m3 TWA (as Sn, except Tin hydride) (listed under Tin inorganic compounds).

2 mg/m3 TWA (as Sn, except Tin oxide) (listed under Tin inorganic compounds).

2 mg/m3 TWA (as Sn, except oxides) (listed under Tin inorganic compounds).


OSHA Vacated PELs: Tin(II) sulfate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties



Physical State : Crystalline powder
Appearance: white - off-white - fine
Odor: none reported
pH: 2.0 (50 g/L aq.sol.)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:360 deg C
Decomposition Temperature:378 deg C
Solubility: 330 g/L (20C)
Specific Gravity/Density:3.95 @ 20C
Molecular Formula:O4SSn
Molecular Weight:214.75

Section 10 - Stability and Reactivity



Chemical Stability: Moisture sensitive.
Conditions to Avoid: Incompatible materials, dust generation, heating to decomposition, exposure to moist air or water.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Oxides of sulfur, tin/tin oxides.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information



RTECS#:      
CAS# 7488-55-3: WT1255000
LD50/LC50:
CAS# 7488-55-3:
     Oral, mouse: LD50 = 2152 mg/kg;
     Oral, rat: LD50 = 2207 mg/kg;
.

Carcinogenicity:
CAS# 7488-55-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: Adverse reproductive effects have occurred in experimental animals.
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information



Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

 

 

US DOT

Canada TDG

Shipping Name:

Not regulated.

Not regulated.

Hazard Class:

 

 

UN Number:

 

 

Packing Group:

 

 

 

Section 15 - Regulatory Information


US FEDERAL


TSCA
     CAS# 7488-55-3 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 7488-55-3: immediate, delayed.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7488-55-3 can be found on the following state right to know lists: Minnesota , (listed as Tin inorganic compounds), Massachusetts .

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.


European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI
Risk Phrases:

     R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection)

     CAS# 7488-55-3: No information available.
Canada - DSL/NDSL
     CAS# 7488-55-3 is listed on Canada 's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2B, D2A.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 7488-55-3 is not listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Nile chemicals be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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