NILE CHEMICALS
Synonyms: ammonium ferric sulfate
CAS No.: 10138-04-2 (Anhydrous) 7783-83-7 (Dodecahydrate)
Molecular Weight: 482.20
Chemical Formula: FeNH4(SO4)2.12H2O
Product Codes: 936
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------ ---------
Ferric Ammonium Sulfate 10138-04-2 99 - 100% Yes
Inhalation: May cause irritation to the respiratory tract. Symptoms may
include coughing, sore throat, labored breathing, and chest pain.
Ingestion: Large oral doses may cause irritation to the gastrointestinal
tract. Low toxicity in small quantities but larger dosages may cause nausea,
vomiting, diarrhea, and black stool. Pink urine discoloration is a strong
indicator of iron poisoning. Liver damage, coma, and death from iron poisoning
has been recorded.
Skin Contact: May cause irritation with redness and pain.
Eye Contact: May cause irritation, redness and pain. Crystals may be
abrasive.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin
disorders or eye problems, or impaired liver, kidney or respiratory function may
be more susceptible to the effects of the substance.
Inhalation: Remove to fresh air. Get medical
attention for any breathing difficulty.
Ingestion: Give several glasses of water to drink to dilute. If large
amounts were swallowed, get medical advice.
Skin Contact: Immediately flush skin with plenty of water for at least 15
minutes. Remove contaminated clothing and shoes. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention if irritation
develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15
minutes, lifting upper and lower eyelids occasionally. Get medical attention if
irritation persists.
Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing
surrounding fire.
Special Information: In the event of a fire, wear full protective
clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits: -ACGIH Threshold Limit
Value (TLV):
1 mg/m3 (TWA) soluble iron salt as Fe
Ventilation System: A system of local and/or general exhaust is
recommended to keep employee exposures below the Airborne Exposure Limits. Local
exhaust ventilation is generally preferred because it can control the emissions
of the contaminant at its source, preventing dispersion of it into the general
work area. Please refer to the ACGIH document, Industrial Ventilation, A
Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded
and engineering controls are not feasible, a half facepiece particulate
respirator (NIOSH type N95 or better filters) may be worn for up to ten times
the exposure limit or the maximum use concentration specified by the appropriate
regulatory agency or respirator supplier, whichever is lowest.. A full-face
piece particulate respirator (NIOSH type N100 filters) may be worn up to 50
times the exposure limit, or the maximum use concentration specified by the
appropriate regulatory agency, or respirator supplier, whichever is lowest. If
oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present,
use a NIOSH type R or P filter. For emergencies or instances where the exposure
levels are not known, use a full-facepiece positive-pressure, air-supplied
respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain
and quick-drench facilities in work area.
Appearance: Pale violet, transparent crystals.
Odor: Odorless.
Solubility: Soluble in water.
Specific Gravity: 1.71
pH: No information found.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 230C (446F) Water
Melting Point: 39 - 41C (102 - 106F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.
Stability: Stable under ordinary conditions of use
and storage.
Hazardous Decomposition Products: May emit toxic fumes of ammonia and
sulfur oxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: No incompatibility data found.
Conditions to Avoid: Heat, moisture, incompatibles.
No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated as a mutagen.
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---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Ferric Ammonium Sulfate No No None
(10138-04-2)
Environmental Fate: No information found.
Environmental Toxicity: No information found.
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Not regulated.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER
EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE
INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
ACCORDINGLY, NILE CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM
USE OF OR RELIANCE UPON THIS INFORMATION.
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