NILE CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Lithium hydroxide
CAS#:
1310-65-2
Chemical
Name: Lithium Hydroxide
Chemical
Formula: LiOH
Section
2: Composition and Information on Ingredients Composition:
Name
CAS #
% by Weight
Lithium
hydroxide
1310-65-2
100
Toxicological
Data on Ingredients: Lithium
hydroxide: ORAL (LD50): Acute: 210 mg/kg [Rat]. 363 mg/kg [Mouse]. DUST (LC50):
Acute: 960 mg/m 4 hours [Rat].
Section
3: Hazards Identification Potential Acute Health Effects:
Very
hazardous in case of skin contact (irritant), of eye contact (irritant), of
ingestion, of inhalation. Hazardous in case of eye contact (corrosive).
Corrosive to eyes and skin. The amount of tissue damage depends on length of
contact. Eye contact can result in corneal damage or blindness. Skin contact can
produce inflammation and blistering. Inhalation of dust will produce irritation
to gastro-intestinal or respiratory tract, characterized by burning, sneezing
and coughing. Severe over-exposure can
produce
lung damage, choking, unconsciousness or death. Inflammation of the eye is
characterized by redness, watering, and itching. Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential
Chronic Health Effects: Hazardous
in case of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys,
gastrointestinal tract, upper respiratory tract, skin, eyes, central nervous
system (CNS). Repeated or
prolonged
exposure to the substance can produce target organs damage. Repeated exposure of
the eyes to a low level of dust can produce eye irritation. Repeated skin
exposure can produce local skin destruction, or dermatitis. Repeated inhalation
of dust can produce varying degree of respiratory irritation or lung damage.
Repeated exposure to a highly toxic material may produce general deterioration
of health by an accumulation in one or many human organs.
Section
4: First Aid Measures Eye Contact:
Check
for and remove any contact lenses. In case of contact, immediately flush eyes
with plenty of water for at least 15 minutes. Cold water may be used. Get
medical attention immediately.
Skin
Contact:In case of
contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Cover the irritated skin with an
emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious
Skin Contact:Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek immediate medical attention.
Inhalation:If
inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention immediately.
Serious
Inhalation:Evacuate the
victim to a safe area as soon as possible. Loosen tight clothing such as a
collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If
the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It
may be hazardous to the person providing aid to give mouth-to-mouth
resuscitation when the inhaled material is toxic, infectious or corrosive. Seek
immediate medical attention.
Ingestion:Do
NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If large quantities of this material
are swallowed, call a physician immediately. Loosen tight clothing such as a
collar, tie, belt or waistband.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: Non-flammable.
Auto-Ignition
Temperature: Not
applicable.
Flash
Points: Not applicable.
Flammable
Limits: Not applicable.
Products
of Combustion: Not
available.
Fire
Hazards in Presence of Various Substances: Not
applicable.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions: Not
applicable.
Special
Remarks on Fire Hazards: Hazardous
Products of Decomposition: Oxides of lithium
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures Small Spill:
Use
appropriate tools to put the spilled solid in a convenient waste disposal
container. If necessary: Neutralize the residue with a dilute solution of acetic
acid.
Large
Spill:Corrosive solid.
Poisonous solid. Stop leak if without risk. Do not get water inside container.
Do not touch spilled material. Use water spray to reduce vapors. Prevent entry
into sewers, basements or confined areas; dike
if needed. Call for assistance on disposal. Neutralize the residue with a dilute
solution of acetic acid. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.
Section
7: Handling and Storage Precautions:
Keep
container dry. Do not ingest. Do not breathe dust. Never add water to this
product. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container
or the label. Avoid contact with skin and eyes. Keep away from incompatibles
such as oxidizing agents, acids.
Storage:
Keep container tightly
closed. Keep container in a cool, well-ventilated area. Air Sensitive
Hygroscopic
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection:Splash goggles.
Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.
Personal
Protection in Case of a Large Spill:Splash
goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained
breathing apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits:STEL: 1 (mg/m3)
[United Kingdom (UK)] CEIL: 1 from AIHA [United States] Consult local
authorities for acceptable
exposure limits.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
(Hygroscopic powder.)
Odor:
Not available.
Taste:
Not available.
Molecular
Weight: 23.95 g/mole
Color:
White.
pH
(1% soln/water): 14
[Basic.]
Boiling
Point: Not available.
Melting
Point: 450°C (842°F)
Critical
Temperature: Not
available.
Specific
Gravity: 2.54 (Water = 1)
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: See solubility
in water, methanol.
Solubility:
Soluble in cold water.
Partially soluble in methanol. Insoluble in diethyl ether.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability:
Exposure
to moist air, water, heat, incompatible materials, heat, air. Air sensitive.
Absorbs carbon dioxide from the air. Hygroscopic. Absorbs moisture or water from
the air.
Incompatibility
with various substances: Reactive
with oxidizing agents, acids.
Corrosivity:
Slightly corrosive in
presence of glass.
Special
Remarks on Reactivity:
Incompatible
with aluminum, carbon dioxide, zinc, aluminum, moisture (hygroscopic). Air
sensitive. Absorbs moisture from the air. Absorbs CO2 from air. Hygroscopic;
keep container tightly closed.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
Will not occur.
Section
11: Toxicological Information
Routes
of Entry: Inhalation.
Ingestion.
Toxicity
to Animals:
WARNING:
THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute
oral toxicity (LD50): 210 mg/kg [Rat]. Acute toxicity of the dust (LC50): 960
mg/m3 4 hours [Rat].
Chronic
Effects on Humans:
May
cause damage to the following organs: kidneys, gastrointestinal tract, upper
respiratory tract, skin, eyes, central nervous system (CNS).
Other
Toxic Effects on Humans:
Extremely
hazardous in case of skin contact (corrosive), of inhalation (lung corrosive).
Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in
case of eye contact (corrosive).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans:
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are less toxic than the product itself.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Waste
must be disposed of in accordance with federal, state and local environmental
control regulations.
Section
14: Transport Information
DOT
Classification: Class 8:
Corrosive material
Identification:
: Lithium hydroxide, solid
UNNA: 2680 PG: II
Special
Provisions for Transport: Not
available.
Section
15: Other Regulatory Information
Federal
and State Regulations: Minnesota:
Lithium hydroxide TSCA 8(b) inventory: Lithium hydroxide
Other
Regulations:
OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
Other
Classifications:
WHMIS
(Canada): CLASS E:
Corrosive solid.
DSCL
(EEC): R20/22- Harmful by
inhalation and if swallowed. R35- Causes severe burns. S22- Do not breathe dust.
S26- In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and
eye/face protection. S45- In case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible).
HMIS
(U.S.A.):
Health
Hazard: 3
Fire
Hazard: 0
Reactivity:
0
Personal
Protection: j
National
Fire Protection Association (U.S.A.):
Health:
3
Flammability:
0
Reactivity:
0
Specific
hazard:
Protective
Equipment:
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