NILE CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Lithium nitrate
CAS#:
7790-69-4
Chemical
Formula: LiNO3
Section
2: Composition and Information on Ingredients Composition:
Name
CAS #
% by Weight
Lithium
nitrate
7790-69-4
100
Toxicological
Data on Ingredients: Lithium
nitrate LD50: Not available. LC50: Not available.
Section
3: Hazards Identification Potential Acute Health Effects:
Very
hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of
eye contact (irritant), of inhalation. Slightly hazardous in case of skin
contact (corrosive). Prolonged exposure may result in skin burns and
ulcerations. Over-exposure by inhalation may cause respiratory irritation.
Potential
Chronic Health Effects:
Very
hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of
eye contact (irritant), of inhalation. Slightly hazardous in case of skin
contact (corrosive). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not
available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available. The substance is toxic to kidneys, the nervous system. Repeated or
prolonged exposure to the substance can produce target organs damage.
Section
4: First Aid Measures Eye Contact:
Check
for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an
eye ointment. Seek medical attention.
Skin
Contact:After contact with
skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated
skin with running water and non-abrasive soap. Be particularly careful to clean
folds, crevices, creases and groin. Cold water may be used. Cover the irritated
skin with an emollient. If irritation persists, seek medical attention.
Serious
Skin Contact: Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek medical attention.
Inhalation:
Allow the victim to rest
in a well ventilated area. Seek immediate medical attention.
Serious
Inhalation: Evacuate the
victim to a safe area as soon as possible. Loosen tight clothing such as a
collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If
the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:Do
not induce vomiting. Loosen tight clothing such as a collar, tie, belt or
waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation.
Seek immediate medical attention.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: Non-flammable.
Auto-Ignition
Temperature: Not
applicable.
Flash
Points: Not applicable.
Flammable
Limits: Not applicable.
Products
of Combustion: Not
available.
Fire
Hazards in Presence of Various Substances: Not
applicable.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions: Not
applicable.
Special
Remarks on Fire Hazards: Not
available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill: Use appropriate
tools to put the spilled solid in a convenient waste disposal container.
Large
Spill:Oxidizing material.
Stop leak if without risk. Avoid contact with a combustible material (wood,
paper, oil, clothing). Keep substance damp using water spray. Do not touch
spilled material. Prevent entry into sewers, basements or confined areas; dike
if needed. Call for assistance on disposal.
Section
7: Handling and Storage Precautions:
Keep
container dry. Keep away from heat. Keep away from sources of ignition. Keep
away from combustible material Do not breathe dust. Never add water to this
product In case of insufficient ventilation, wear suitable respiratory equipment
If you feel unwell, seek medical attention and show the label when possible.
Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing
agents, reducing agents, combustible materials, organic materials.
Storage:
Oxidizing materials should
be stored in a separate safety storage cabinet or room.
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection: Splash
goggles. Lab coat. Dust respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.
Personal
Protection in Case of a Large Spill: Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
(Crystalline solid.)
Odor:
Not available.
Taste:
Not available.
Molecular
Weight: 68.95 g/mole
Color:
Colorless.
pH
(1% soln/water): 7
[Neutral.]
Boiling
Point: Decomposes.
Melting
Point: 255°C (491°F)
Critical
Temperature: Not
available.
Specific
Gravity: 2.38 (Water = 1)
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: See solubility
in water, methanol.
Solubility:
Easily soluble in cold
water. Soluble in methanol.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Not
available.
Incompatibility
with various substances: Highly
reactive with reducing agents, combustible materials, organic materials.
Corrosivity:
Non-corrosive in presence
of glass.
Special
Remarks on Reactivity: Not
available.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
No.
11:
Toxicological Information
Routes
of Entry: Eye contact.
Inhalation. Ingestion.
Toxicity
to Animals:
LD50:
Not available. LC50: Not available.
Chronic
Effects on Humans: The
substance is toxic to kidneys, the nervous system.
Other
Toxic Effects on Humans: Very
hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of
inhalation. Slightly hazardous in case of skin contact (corrosive).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Human:
passes through the placenta, excreted in maternal milk.
Special
Remarks on other Toxic Effects on Humans: Not
available.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Section
14: Transport Information
DOT
Classification: CLASS 5.1:
Oxidizing material.
Identification:
: Lithium nitrate : UN2722
PG: III
Special
Provisions for Transport: Marine
Pollutant
Section
15: Other Regulatory Information Federal and State Regulations:
Pennsylvania
RTK: Lithium nitrate Massachusetts RTK: Lithium nitrate TSCA 8(b) inventory:
Lithium nitrate
Other
Regulations: OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other
Classifications:
WHMIS
(Canada): CLASS C:
Oxidizing material.
DSCL
(EEC): R36/38- Irritating
to eyes and skin.
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 0
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
0
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is inadequate. Splash
goggles.
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