NILE CHEMICALS
1.
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1
Product identifiers
Product
name : Mercury dibromofluorescein disodium salt
Index-No.
: 080-004-00-7
CAS-No.
: 129-16-8
2.
HAZARDS IDENTIFICATION
Classification
of the substance or mixture
Acute
toxicity, Inhalation (Category 2)
Acute
toxicity, Dermal (Category 1)
Acute
toxicity, Oral (Category 2)
Specific
target organ toxicity - repeated exposure (Category 2)
Acute
aquatic toxicity (Category 1)
Chronic
aquatic toxicity (Category 1)
3.
COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Synonyms
: Merbromin
2′,7′-Dibromo-5′-(hydroxymercurio)fluorescein
Mercurochrome
Formula
: C20H8Br2HgNa2O6
Molecular
Weight : 750,65 g/mol
Component
Concentration
Merbromin
CAS-No.
EC-No.
Index-No.
129-16-8
204-933-6
080-004-00-7
4.
FIRST AID MEASURES
Description
of first aid measures
General
advice Consult a physician. Show this
safety data sheet to the doctor in attendance.
If
inhaled If breathed in, move person into
fresh air. If not breathing, give artificial respiration. Consult a physician.
In
case of skin contact Wash off with soap and
plenty of water. Take victim immediately to hospital. Consult a physician.
In
case of eye contact Flush eyes with water
as a precaution.
If
swallowed Never give anything by mouth to
an unconscious person. Rinse mouth with water. Consult a physician.
Most
important symptoms and effects, both acute and delayed Central
nervous system depression
Indication
of any immediate medical attention and special treatment needed no
data available
5.
FIREFIGHTING MEASURES
Extinguishing
media
Suitable
extinguishing media Use water spray,
alcohol-resistant foam, dry chemical or carbon dioxide.
Special
hazards arising from the substance or mixture Carbon
oxides, Hydrogen bromide gas, Sodium oxides, Mercury/mercury oxides.
Advice
for firefighters Wear self contained
breathing apparatus for fire fighting if necessary.
Further
information no data available
6.
ACCIDENTAL RELEASE MEASURES
Personal
precautions, protective equipment and emergency procedures Wear
respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or
gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid
breathing dust.
Environmental
precautions Prevent further leakage or
spillage if safe to do so. Do not let product enter drains. Discharge into the
environment
must be avoided.
Methods
and materials for containment and cleaning up Pick
up and arrange disposal without creating dust. Sweep up and shovel. Keep in
suitable, closed containers for disposal.
Reference
to other sections For disposal see section
13.
7.
HANDLING AND STORAGE
Precautions
for safe handling Avoid contact with skin
and eyes. Avoid formation of dust and aerosols.
Provide
appropriate exhaust ventilation at places where dust is formed.
Conditions
for safe storage, including any incompatibilities Store
in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific
end uses no data available
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control
parameters Components with workplace
control parameters
Exposure
controls
Appropriate
engineering controls Avoid contact with
skin, eyes and clothing. Wash hands before breaks and immediately after handling
the
product.
Personal
protective equipment
Eye/face
protection Face shield and safety glasses
Use equipment for eye protection tested and approved under
appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin
protection Handle with gloves. Gloves must
be inspected prior to use. Use proper glove removal technique
(without
touching glove's outer surface) to avoid skin contact with this product. Dispose
of
contaminated
gloves after use in accordance with applicable laws and good laboratory
practices.
Wash
and dry hands.
The
selected protective gloves have to satisfy the specifications of EU Directive
89/686/EEC and
the
standard EN 374 derived from it.
Body
Protection Complete suit protecting against
chemicals, The type of protective equipment must be selected
according
to the concentration and amount of the dangerous substance at the specific
workplace.
Respiratory
protection Where risk assessment shows
air-purifying respirators are appropriate use a full-face particle
respirator
type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to
engineering
controls.
If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use
respirators
and components tested and approved under appropriate government standards such
as
NIOSH (US) or CEN (EU).
9.
PHYSICAL AND CHEMICAL PROPERTIES
Information
on basic physical and chemical properties
a)
Appearance Form: crystalline Colour: dark green
b)
Odour no data available
c)
Odour Threshold no data available
d)
pH 8,5 - 9,0
e)
Melting point/freezing point Melting point/range: >= 300 °C
f)
Initial boiling point and boiling range no data available
g)
Flash point no data available
h)
Evaporation rate no data available
i)
Flammability (solid, gas) no data available
j)
Upper/lower flammability or explosive limits no data available
k)
Vapour pressure no data available
l)
Vapour density no data available
m)
Relative density no data available
n)
Water solubility no data available
o)
Partition coefficient: noctanol/water no data available
p)
Autoignition temperature no data available
q)
Decomposition temperature no data available
r)
Viscosity no data available
s)
Explosive properties no data available
t)
Oxidizing properties no data available
Other
safety information
Bulk
density 0,85 - 0,90 g/l
10.
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical
stability no data available
Possibility
of hazardous reactions no data available
Conditions
to avoid no data available
Incompatible
materials Strong oxidizing agents, Strong
acids
Hazardous
decomposition products Other decomposition
products - no data available
11.
TOXICOLOGICAL INFORMATION
Information
on toxicological effects
Acute
toxicity LD50 Intravenous - mouse - 50
mg/kg
Skin
corrosion/irritation no data available
Serious
eye damage/eye irritation no data available
Respiratory
or skin sensitization no data available
Germ
cell mutagenicity no data available
Carcinogenicity
IARC: No component of this product present
at levels greater than or equal to 0.1% is identified as
probable,
possible or confirmed human carcinogen by IARC.
Reproductive
toxicity no data available
Specific
target organ toxicity - single exposure no
data available
Specific
target organ toxicity - repeated exposure May
cause damage to organs through prolonged or repeated exposure.
Aspiration
hazard no data available
Potential
health effects Inhalation May be fatal if
inhaled. May cause respiratory tract irritation.
Ingestion
May be fatal if swallowed.
Skin
May be fatal if absorbed through skin. May
cause skin irritation.
Eyes
May cause eye irritation.
Signs
and Symptoms of Exposure Central nervous
system depression
Additional
Information RTECS: LM5250000
12.
ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence
and degradability no data available
Bioaccumulative
potential no data available
Mobility
in soil no data available
Results
of PBT and vPvB assessment no data
available
Other
adverse effects Very toxic to aquatic life
with long lasting effects.
13.
DISPOSAL CONSIDERATIONS
Waste
treatment methods
Product
Offer surplus and non-recyclable solutions
to a licensed disposal company. Dissolve or mix the material
with
a combustible solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber.
Contaminated
packaging Dispose of as unused product.
14.
TRANSPORT INFORMATION
UN
number
ADR/RID:
2025 IMDG: 2025 IATA: 2025
UN
proper shipping name
ADR/RID:
MERCURY COMPOUND, SOLID, N.O.S. (Merbromin)
IMDG:
MERCURY COMPOUND, SOLID, N.O.S. (Merbromin)
IATA:
Mercury compound, solid, n.o.s. (Merbromin)
Transport
hazard class(es)
ADR/RID:
6.1 IMDG: 6.1 IATA: 6.1
Packaging
group
ADR/RID:
II IMDG: II IATA: II
Environmental
hazards
ADR/RID:
yes IMDG Marine pollutant: yes IATA: no
Special
precautions for user
no
data available
15.
REGULATORY INFORMATION
This
safety datasheet complies with the requirements of Regulation (EC) No.
1907/2006.
Safety,
health and environmental regulations/legislation specific for the substance or
mixture
no
data available
Chemical
Safety Assessment no data available
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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