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Identification of substance:
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Product
details: Manganese (II) sulfate Mono
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Stock number:
131123
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Manufacturer/Supplier:
NILE CHEMICALS
Phone: 91 22-56313162
Web Site: www.nilechemicals.com
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2 Composition/Data on components:
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Chemical
characterization:
Description: (CAS#)
Manganese (II) sulfate, monohydrate
(CAS# 10034-96-5): 100%
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Identification
number(s):
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EINECS Number:
232-089-9
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EU Number:
025-003-00-4
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3 Hazards identification
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Hazard
description:Xn
Harmful
N Dangerous for the environment
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Information
pertaining to particular dangers for man and environment
R 48/20/22 Harmful: danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
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Classification
system
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HMIS ratings
(scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 0
Reactivity = 1
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4 First aid measures
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After
inhalation:Supply
fresh air. If required, provide artificial respiration. Keep patient
warm.
Seek immediate medical advice.
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After skin
contact
Immediately wash with water and soap and rinse thoroughly. Seek
immediate medical advice.
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After eye
contact
:Rinse opened eye for several minutes under running water. Then consult
a doctor.
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After
swallowing
Seek immediate medical advice.
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5 Fire fighting measures
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Suitable
extinguishing agents
:Product is not flammable. Use fire fighting measures that suit the
surrounding fire.
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Special hazards
caused by the material, its products of combustion or
resulting gases:
In case of fire, the following can be released:
Metal oxide fume, Slfur oxides (SOx)
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Protective
equipment:Wear
self-contained respirator.Wear fully protective impervious suit.
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6 Accidental release measures
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Person-related
safety precautions:Wear
protective equipment. Keep unprotected persons away. Ensure adequate
ventilation
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Measures for
environmental protection:Do
not allow material to be released to the environment without proper
governmental permits.
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Measures for
cleaning/collecting:
Dispose contaminated material as waste according to item 13.Ensure
adequate ventilation.
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Additional
information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
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7 Handling and storage
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Handling
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Information for
safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Prevent formation of dust.
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Information
about protection against explosions and fires:
The product is not flammable
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Storage
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Requirements to
be met by storerooms and receptacles:No
special requirements.
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Information
about storage in one common storage facility:Store
away from oxidizing agents.
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Further
information about storage conditions:
Keep container tightly sealed.Store in cool, dry conditions in well
sealed containers.
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8 Exposure controls and personal protection
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Additional
information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals
and having an average face velocity of at least 100 feet per minute.
Components with limit values that require monitoring at the
workplace:
Manganese, elemental & inorganic compounds (as Mn)
mg/m3
ACGIH TLV 0.2
Austria MAK 5
Belgium TWA 1; 3-STEL (fume)
Denmark TWA 2.5
Finland TWA 0.5
France VME 1 (fume)
Germany MAK 0.55
Japan OEL 0.3 (respirable dust)
Korea TLV 0.2
Netherlands MAC-TGG 1; 3-MAC-K
Norway TWA 1
Russia 0.2-STEL (fume)
Sweden NGV 1; 2.5-TGV (resp. dust)
2.5; 5-TGV (total dust)
Switzerland MAK-W 5
1 (fume)
United Kingdom TWA 5
1; 3-STEL (fume)
USA PEL 5-Ceiling (fume)
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Additional
information:
No data
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Personal
protective equipment
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General
protective and hygienic measures
The usual precautionary measures for handling chemicals should be
followed.Keep away from foodstuffs, beverages and feed.Remove all soiled
and contaminated clothing immediately. Wash hands before breaks and at
the end of work. Store protective clothing separately.
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Breathing
equipment:Use
suitable respirator when high concentrations are present.
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Protection of
hands:Impervious
gloves
Check protective gloves prior to each use for their proper condition.
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Material of
gloves
The selection of suitable gloves not only depends on the material, but
also on quality. Quality will vary from manufacturer to manufacturer.
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Eye protection:
Safety glasses
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Body
protection:
Protective work clothing.
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9 Physical and chemical properties:
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General
Information
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Form:
Powder
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Color:
Pink
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Odor:
Not determined
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Value/Range Unit Method
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Change in
condition
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Melting
point/Melting range:
Not determined
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Boiling
point/Boiling range:
Not determined
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Sublimation
temperature / start:
Not determined
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Flash point:
Not applicable
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Ignition
temperature:
Not determined
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Decomposition
temperature:
Not determined
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Danger of
explosion:
Product does not present an explosion hazard.
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Explosion
limits:
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Lower:
Not determined
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Upper:
Not determined
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Vapor pressure:
Not determined
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Density:
at 20 ° C 2.95 g/cm³
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Solubility in /
Miscibility with
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Water:
Not determined
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10 Stability and reactivity
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Thermal
decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.
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Materials to be
avoided:
Oxidizing agents
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Dangerous
reactions
No dangerous reactions known
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Dangerous
products of decomposition:
Metal oxide fume, Sulfur oxides (SOx)
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11 Toxicological information
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Acute toxicity:
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Primary
irritant effect:
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on the skin:
Irritant to skin and mucous membranes.
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on the eye:
Irritating effect.
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Sensitization:
No sensitizing effects known.
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Subacute to
chronic toxicity:Chronic
exposure to manganese may cause impairment to the central nervous
system. Symptoms include sluggishness, sleepiness, muscle weakness,
loss of facial muscle control, edema, emotional disturbances, spastic
gait and falling. Chronic manganese poisoning may develop after as
little as three months of heavy exposure but usually cases develop after
one to three years of exposure,
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Additional
toxicological information:To
the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
EPA-D: Not classifiable as to human carcinogenicity: inadequate human
and animal evidence of carcinogenicity or no data are available.
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12 Ecological information:
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Ecotoxical
effects:
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Remark:
Toxic for fish
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General notes:
Also poisonous for fish and plankton in water bodies.
Do not allow material to be released to the environment without proper
governmental permits.Toxic for aquatic organisms
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13 Disposal considerations
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Product:
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Recommendation
Consult state, local or national regulations to ensure proper disposal.
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Uncleaned
packagings:
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Recommendation:
Disposal must be made according to official regulations.
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14 Transport information
Not a
hazardous material for transportation.
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DOT
regulations:
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Hazard class:
None
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Land transport
ADR/RID (cross-border)
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ADR/RID class:
None
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Maritime
transport IMDG:
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IMDG Class:
None
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Air transport
ICAO-TI and IATA-DGR:
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ICAO/IATA
Class:
None
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Transport/Additional information:
Not dangerous according to the above specifications.
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15 Regulations
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Product related
hazard informations:
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Hazard symbols:
Xn Harmful N Dangerous for the environment
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Risk phrases:
48/20/22 Harmful: danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment
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Safety phrases:
22 Do not breathe dust.
61 Avoid release to the environment. Refer to special
instructions/Safety data sheets
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National
regulations:All
components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical substance
Inventory. All components of this product are listed on the Canadian
Domestic Substances List (DSL).
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Information
about limitation of use:For
use only by technically qualified individuals. This product contains
manganese and is subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right to Know Act of 1986 and
40CFR372.
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16 Other information:
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Employers
should use this information only as a supplement to other information
gathered by them, and should make independent judgement of suitability
of this information to ensure proper use and protect the health and
safety of employees. This information is furnished without warranty,
and any use of the product not in conformance with this Material Safety
Data Sheet, or in combination with any other product or process, is the
responsibility of the user.
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