NILE CHEMICALS
Synonyms: 1-H-Benzotriazole; Cobratec 99;
1,2-Aminozophenylene; Benzene Azimide; 1,2,3-Benzotriazole
CAS No.: 95-14-7
Molecular Weight: 119.12
Chemical Formula: C6H5N3
Health Rating: 1 - Slight
Flammability Rating: 1 - Slight
Reactivity Rating: 1 - Slight
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Green (General Storage)
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Potential Health Effects
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Information on the human health effects from exposure to this substance is
limited.
Inhalation: May cause irritation to the respiratory tract. Symptoms may
include coughing, sore throat, labored breathing, and chest pain.
Ingestion: May cause irritation to the gastrointestinal tract. Symptoms
may include nausea, vomiting and diarrhea.
Skin Contact: May cause irritation with redness and pain.
Eye Contact: May cause irritation, redness and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions:
No information found.
Inhalation:Remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion:Give large amounts of water to drink. Never give anything by
mouth to an unconscious person. Get medical attention.
Skin Contact:Immediately flush skin with plenty of water for at least 15
minutes. Remove contaminated clothing and shoes. Get medical attention. Wash
clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:Immediately flush eyes with plenty of water for at least 15
minutes, lifting lower and upper eyelids occasionally. Get medical attention
immediately.
Fire:Flash point: 171C (340F) CC
Autoignition temperature: 400C (752F)
Explosion: Above the flash point, explosive vapor-air mixtures may be
formed. May explode during vacuum distillation. Fine dust dispersed in air in
sufficient concentrations, and in the presence of an ignition source is a
potential dust explosion hazard.
Fire Extinguishing Media:Water spray, dry chemical, alcohol foam, or
carbon dioxide.
Special Information:In the event of a fire, wear full protective clothing
and NIOSH-approved self-contained breathing apparatus with full facepiece
operated in the pressure demand or other positive pressure mode.
Remove all sources of ignition. Ventilate area of leak or
spill. Keep unnecessary and unprotected people away from area of spill. Wear
appropriate personal protective equipment as specified in Section 8. Spills:
Pick up and place in a suitable container for reclamation or disposal, using a
method that does not generate dust.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Do not vacuum distill. Separate from incompatibles. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is
recommended to keep employee exposures as low as possible. Local exhaust
ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work
area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of
Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to dust or mist is apparent and engineering
controls are not feasible, a particulate respirator (NIOSH type N95 or better
filters) may be worn. If oil particles (e.g. lubricants, cutting fluids,
glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or
instances where the exposure levels are not known, use a full-face
positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators
do not protect workers in oxygen-deficient atmospheres.
Skin Protection:Wear impervious protective clothing, including boots,
gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield
where splashing is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Appearance: Off-white powder.
Odor: Slight characteristic odor.
Solubility: Moderate (1-10%)
Specific Gravity: 1.36
pH: No information found.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 204C (399F) @ 15 mm Hg.
Melting Point: 98.5C (208F)
Vapor Density (Air=1): 4.1
Vapor Pressure (mm Hg): 0.04 @ 20C (68F)
Evaporation Rate (BuAc=1): No information found.
Stability: Stable under ordinary conditions of use
and storage. May explode during vacuum distillation. Can violently decompose
above 285C. Avoid temperatures above 185C.
Hazardous Decomposition Products: May produce oxides of carbon and oxides
of nitrogen when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Heat, ignition sources and in compatibililites.
Environmental Fate: No information found.
Environmental Toxicity: No information found.
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Not regulated.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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