NILE CHEMICALS

2-BROMO ANILINE

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifiers

Product name : 2-Bromoaniline

CAS-No. : 615-36-1

Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Manufacture of substances

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Acute toxicity, Oral (Category 4)

Acute toxicity, Dermal (Category 3)

Specific target organ toxicity - repeated exposure (Category 2)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Toxic in contact with skin and if swallowed. Danger of cumulative effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

Pictogram

Signal word Danger

Hazard statement(s)

H302 Harmful if swallowed.

H311 Toxic in contact with skin.

H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statement(s)

P280 Wear protective gloves/ protective clothing.

P312 Call a POISON CENTER or doctor/ physician if you feel unwell.

Supplemental Hazard Statements none

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)

R-phrase(s)

R24/25 Toxic in contact with skin and if swallowed.

R33 Danger of cumulative effects.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

S-phrase(s)

S36/37 Wear suitable protective clothing and gloves.

S45 In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

S61 Avoid release to the environment. Refer to special instructions/ Safety

data sheets.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Formula : C6H6BrN

Molecular Weight : 172,02 g/mol

Component Concentration

2-Bromoaniline

CAS-No.

EC-No.

615-36-1

210-421-3

4. FIRST AID MEASURES

Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact Flush eyes with water as a precaution.

If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Indication of any immediate medical attention and special treatment needed no data available

5. FIRE-FIGHTING MEASURES

Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx), Hydrogen bromide gas

dvice for firefighters Wear self contained breathing apparatus for fire fighting if necessary.

Further information no data available

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

Reference to other sections For disposal see section 13.

7. HANDLING AND STORAGE

Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.

Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Specific end uses no data available

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Exposure controls

Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected

according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle

respirator type N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering

controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use

respirators and components tested and approved under appropriate government standards such as

NIOSH (US) or CEN (EU).

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

a) Appearance Form: Solidified mass or fragments Colour: light brown

b) Odour no data available

c) Odour Threshold no data available

d) pH no data available

e) Melting point/freezing point Melting point/range: 24 - 28 °C - lit.

f) Initial boiling point and boiling range 229 °C - lit.

g) Flash point no data available

h) Evaporation rate no data available

i) Flammability (solid, gas) no data available

j) Upper/lower flammability or explosive limits no data available

k) Vapour pressure no data available

l) Vapour density no data available

m) Relative density 1,52 g/cm3 at 25 °C

n) Water solubility no data available

o) Partition coefficient: noctanol/ water log Pow: 2,11

p) Autoignition temperature no data available

q) Decomposition temperature no data available

r) Viscosity no data available

s) Explosive properties no data available

t) Oxidizing properties no data available

Other safety information

no data available

10. STABILITY AND REACTIVITY

Reactivity no data available

 Chemical stability no data available

 Possibility of hazardous reactions no data available

 Conditions to avoid no data available

 Incompatible materials acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents

 Hazardous decomposition products Other decomposition products - no data available

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity no data available

Skin corrosion/irritation no data available

Serious eye damage/eye irritation no data available

Respiratory or skin sensitization no data available

Germ cell mutagenicity no data available

Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity no data available

Specific target organ toxicity - single exposure no data available

Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard  no data available

Potential health effects Inhalation Harmful if inhaled. May cause respiratory tract irritation.

Ingestion Harmful if swallowed.

Skin Toxic if absorbed through skin. May cause skin irritation.

Eyes May cause eye irritation.

Signs and Symptoms of Exposure Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Additional Information RTECS: Not available

12. ECOLOGICAL INFORMATION

Toxicity Toxicity to daphnia and other aquatic invertebrates.

EC50 - Daphnia magna (Water flea) - 3 mg/l - 48 h

Persistence and degradability no data available

Bioaccumulative potential no data available

Mobility in soil no data available

Results of PBT and vPvB assessment no data available

Other adverse effects Toxic to aquatic life. no data available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

UN number

ADR/RID: 2811 IMDG: 2811 IATA: 2811

UN proper shipping name

ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (2-Bromoaniline)

IMDG: TOXIC SOLID, ORGANIC, N.O.S. (2-Bromoaniline)

IATA: Toxic solid, organic, n.o.s. (2-Bromoaniline)

Transport hazard class(es)

ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

Packaging group

ADR/RID: III IMDG: III IATA: III

Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

Special precautions for user

no data available

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

Chemical Safety Assessment

no data available

16. Other Information

Disclaimer: Nile Chemicals. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
 

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