NILE
CHEMICALS
NILE
CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Para Bromoaniline
CAS#:
106-40-1
Synonym:
4-Bromoaniline
Chemical
Formula: C6H6BrN
Section
2: Composition and Information on Ingredients Composition:
Name
CAS # % by Weight
Bromoaniline
(para-) 106-40-1 100
Toxicological
Data on Ingredients: Bromoaniline (para-):
ORAL (LD50): Acute: 456 mg/kg [Rat]. 289 mg/kg [Mouse].
Section
3: Hazards Identification Potential Acute Health Effects:
Very
hazardous in case of skin contact (irritant), of eye contact (irritant), of
ingestion, of inhalation. Slightly hazardous in case of skin contact
(permeator). Inflammation of the eye is characterized by redness, watering, and
itching. Skin inflammation is characterized by itching, scaling, reddening, or,
occasionally, blistering.
Potential
Chronic Health Effects: CARCINOGENIC
EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS:
Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged
exposure is not known to aggravate medical condition.
Section
4: First Aid Measures Eye Contact: Check
for and remove any contact lenses. In case of contact, immediately flush eyes
with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin
Contact: In case of contact, immediately
flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Cover the irritated skin with an emollient.
Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention immediately.
Serious
Skin Contact: Wash with a disinfectant soap
and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation: If
inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention.
Serious
Inhalation: Not available.
Ingestion : Do
NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If large quantities of this material
are swallowed, call a physician immediately. Loosen tight clothing such as a
collar, tie, belt or waistband.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: May be combustible at high
temperature.
Auto-Ignition
Temperature: Not available.
Flash
Points: Not available.
Flammable
Limits: Not available.
Products
of Combustion: These products are carbon
oxides (CO, CO2), halogenated compounds.
Fire
Hazards in Presence of Various Substances: Not
available.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions: SMALL
FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special
Remarks on Fire Hazards: Not available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill: Use appropriate tools to put the
spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local
and regional authority requirements.
Large
Spill: Use a shovel to put the material
into a convenient waste disposal container. Finish cleaning by spreading water
on the contaminated surface and allow to evacuate through the sanitary system.
Section
7: Handling and Storage Precautions:
Keep
away from heat. Keep away from sources of ignition. Empty containers pose a fire
risk, evaporate the residue under a fume hood. Ground all equipment containing
material. Do not ingest. Do not breathe dust. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical
advice immediately and show the container or the label. Avoid contact with skin
and eyes.
Storage:
Keep container tightly closed. Keep
container in a cool, well-ventilated area.
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection: Splash goggles. Lab coat. Dust
respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal
Protection in Case of a Large Spill:
Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid. (Crystalline
solid.)
Odor:
Sweetish.
Taste:
Not available.
Molecular
Weight: 172.03 g/mole
Color:
White.
pH
(1% soln/water): Not applicable.
Boiling
Point: Decomposes.
Melting
Point: 66°C (150.8°F)
Critical
Temperature: Not available.
Specific
Gravity: 1.497 (Water = 1)
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not available.
Ionicity
(in Water): Not available.
Dispersion
Properties: Not available.
Solubility:
Insoluble in cold water.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not available.
Conditions
of Instability: Not available.
Incompatibility
with various substances: Not available.
Corrosivity:
Non-corrosive in presence of glass.
Special
Remarks on Reactivity: Not available.
Special
Remarks on Corrosivity: Not available.
Polymerization:
Will not occur.
Section
11: Toxicological Information
Routes
of Entry: Eye contact. Inhalation.
Ingestion.
Toxicity
to Animals: Acute oral toxicity (LD50): 289
mg/kg [Mouse].
Chronic
Effects on Humans: Not available.
Other
Toxic Effects on Humans: Very hazardous in
case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous
in case of skin contact (permeator).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans: Not
available.
Section
12: Ecological Information Ecotoxicity: Not
available.
BOD5
and COD: Not available.
Products
of Biodegradation: Possibly hazardous short
term degradation products are not likely. However, long term degradation
products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Section
14: Transport Information
DOT
Classification: Not a DOT controlled
material (United States).
Identification:
Not applicable.
Special
Provisions for Transport: Not applicable.
Section
15: Other Regulatory Information
Federal
and State Regulations: TSCA 8(b) inventory:
Bromoaniline (para-)
Other
Regulations: OSHA: Hazardous by definition
of Hazard Communication Standard (29 CFR 1910.1200).
Other
Classifications:
WHMIS
(Canada): CLASS D-1B: Material causing
immediate and serious toxic effects (TOXIC). CLASS D-2B: Material causing other
toxic effects (TOXIC).
DSCL
(EEC):
R22-
Harmful if swallowed. R38- Irritating to skin. R41- Risk of serious damage to
eyes.
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 1
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
1
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is inadequate. Splash
goggles.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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