NILE
CHEMICALS
NILE
CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: 4-Nitroaniline
CAS#:
100-01-6
Chemical
Formula: C6H6N2O2
Section
2: Composition and Information on Ingredients Composition:
Name
CAS #
% by Weight
4-Nitroaniline
100-01-6
100
Section
3: Hazards Identification Potential Acute Health Effects:
Very
hazardous in case of skin contact (irritant), of eye contact (irritant), of
ingestion. Hazardous in case of skin contact (permeator), of inhalation (lung
irritant). Slightly hazardous in case of skin contact (corrosive). Inflammation
of the eye is characterized by redness, watering, and itching. Skin inflammation
is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential
Chronic Health Effects:CARCINOGENIC
EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not
classifiable for human.) by IARC. MUTAGENIC EFFECTS: Not available. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or
prolonged exposure is not known to aggravate medical condition.
Section
4: First Aid Measures Eye Contact:Check
for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an
eye ointment. Seek medical attention.
Skin
Contact: After contact
with skin, wash immediately with plenty of water. Gently and thoroughly wash the
contaminated skin with running water and non-abrasive soap. Be particularly
careful to clean folds, crevices, creases and groin. Cover the irritated skin
with an emollient. If irritation persists, seek medical attention. Wash
contaminated clothing before reusing.
Serious
Skin Contact: Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek immediate medical attention.
Inhalation:
Allow the victim to rest
in a well ventilated area. Seek immediate medical attention.
Serious
Inhalation: Evacuate the
victim to a safe area as soon as possible. Loosen tight clothing such as a
collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If
the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do not induce vomiting.
Examine the lips and mouth to ascertain whether the tissues are damaged, a
possible indication that the toxic material was ingested; the absence of such
signs, however, is not conclusive. Loosen tight clothing such as a collar, tie,
belt or waistband. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek immediate medical attention.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: May be
combustible at high temperature.
Auto-Ignition
Temperature: Not
available.
Flash
Points: CLOSED CUP: 198.9°C
(390°F).
Flammable
Limits: Not available.
Products
of Combustion: These
products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire
Hazards in Presence of Various Substances: Slightly
flammable to flammable in presence of organic materials.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available. Slightly explosive to explosive in presence of heat.
Fire
Fighting Media and Instructions:
SMALL
FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special
Remarks on Fire Hazards: Not
available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill: Use appropriate
tools to put the spilled solid in a convenient waste disposal container.
Large
Spill: Use a shovel to put
the material into a convenient waste disposal container. Be careful that the
product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.
Section
7: Handling and Storage Precautions:
Keep
container dry. Keep away from heat. Keep away from sources of ignition. Empty
containers pose a fire risk, evaporate the residue under a fume hood. Ground all
equipment containing material. Do not ingest. Do not breathe dust. Never add
water to this product In case of insufficient ventilation, wear suitable
respiratory equipment If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes
Storage:
Keep container dry. Keep
in a cool place. Ground all equipment containing material. Keep container
tightly closed. Keep in a cool, well-ventilated place. Combustible materials
should be stored away from extreme heat and away from strong oxidizing agents.
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection: Splash
goggles. Lab coat. Dust respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.
Personal
Protection in Case of a Large Spill:
Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits: TWA: 1 CEIL: 2
(ppm) TWA: 6 CEIL: 12 (mg/m3) Consult local authorities for acceptable exposure
limits.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
Odor:
Not available.
Taste:
Not available.
Molecular
Weight: 138.12 g/mole
Color:
Yellow.
pH
(1% soln/water): Not
available.
Boiling
Point: 331.7°C (629.1°F)
Melting
Point: 148.5°C (299.3°F)
Critical
Temperature: Not
available.
Specific
Gravity: 1.424 (Water = 1)
Vapor
Pressure: Not applicable.
Vapor
Density: 4.77 (Air = 1)
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: Not available.
Solubility:
Very slightly soluble in
cold water.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Not
available.
Incompatibility
with various substances: Not
available.
Corrosivity:
Non-corrosive in presence
of glass.
Special
Remarks on Reactivity: Not
available.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
No.
Section
11: Toxicological Information
Routes
of Entry: Absorbed through
skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity
to Animals: Acute oral
toxicity (LD50): 450 mg/kg [Guinea pig].
Chronic
Effects on Humans:
CARCINOGENIC
EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not
classifiable for human.) by IARC.
Other
Toxic Effects on Humans:
Very
hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of
skin contact (permeator), of inhalation (lung irritant). Slightly hazardous in
case of skin contact (corrosive).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans: Not
available.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Section
14: Transport Information
DOT
Classification:
Identification:
Special
Provisions for Transport: Not
available.
Section
15: Other Regulatory Information Federal and State Regulations:
WHMIS
(Canada):
CLASS
D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS
D-2B: Material causing other toxic effects (TOXIC).
DSCL
(EEC): R37/38- Irritating
to respiratory system and skin. R41- Risk of serious damage to eyes.
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 1
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
1
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate
respirator when ventilation is inadequate. Splash goggles.
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