NILE CHEMICALS
ACETAMIDE
1.
Product Identification
Synonyms:
Acetic acid
amide; ethanamide; methane carboxamide
CAS
No.: 60-35-5
Molecular
Weight: 59.08
Chemical
Formula: CH3CONH2
2.
Composition/Information on Ingredients
Ingredient
CAS No
Percent
Hazardous
-----------
-------------- --------------
------------
Acetamide
60-35-5
100%
Yes
3.
Hazards Identification
Emergency
Overview
-----------------------------------------------------------------------------------------------------------
Health
Rating: 3 - Severe (Cancer Causing)
Flammability
Rating: 1 - Slight
Reactivity
Rating: 1 - Slight
Contact
Rating: 1 - Slight
Storage Color Code: Blue (Health hazard)
Potential
Health Effects
----------------------------------
Inhalation:May
cause irritation to the respiratory tract.
Ingestion:Extremely
large oral doses may produce gastro-intestinal disturbances.
Skin
Contact:Causes
mild irritation.
Eye
Contact:Causes
severe irritation and corneal damage.
Chronic
Exposure:Repeated
ingestion may cause liver tumors. See toxicity data.
Aggravation
of Pre-existing Conditions:No
information found.
4.
First Aid Measures
Inhalation:Remove
to fresh air. Get medical attention for any breathing difficulty.
Ingestion:Give
several glasses of water to drink to dilute. If large amounts were swallowed,
get medical advice. Never give anything by mouth to an unconscious person.
Skin
Contact:
Eye
Contact: Immediately
flush eyes with plenty of water for at least 15 minutes, lifting lower and upper
eyelids occasionally. Get medical attention immediately.
5
Fire Fighting Measures
Fire:
As with most
organic solids, fire is possible at elevated temperatures or by contact with an
ignition source. Minimum dust cloud ignition temperature: 560C (1040F).
Explosion:Fine
dust dispersed in air in sufficient concentrations, and in the presence of an
ignition source is a potential dust explosion hazard.
Fire
Extinguishing Media:Water
spray, dry chemical, alcohol foam, or carbon dioxide.
Special
Information: Wear
full protective clothing and breathing equipment for high-intensity fire or
potential explosion conditions.
6.
Accidental Release Measures
Remove
all sources of ignition. Ventilate area of leak or spill. Wear appropriate
personal protective equipment as specified in Section 8. Spills: Clean up spills
in a manner that does not disperse dust into the air. Use non-sparking tools and
equipment. Reduce airborne dust and prevent scattering by moistening with water.
Pick up spill for recovery or disposal and place in a closed container. US
Regulations (CERCLA) require reporting spills and releases to soil, water and
air in excess of reportable quantities.
7.
Handling and Storage
Keep
in a tightly closed container, stored in a cool, dry, ventilated area. Protect
against physical damage. Iso late from any source of heat or ignition. Isolate
from oxidizing materials. Wear special protective equipment (Sec. 8) for
maintenance break-in or where exposures may exceed established exposure levels.
Wash hands, face, forearms and neck when exiting restricted areas. Shower,
dispose of outer clothing, change to clean garments at the end of the day. Avoid
cross-contamination of street clothes. Wash hands before eating and do not eat,
drink, or smoke in work place. Avoid dust formation and control ignition
sources. Employ grounding, venting and explosion relief provisions in accord
with accepted engineering practices in any process capable of generating dust
and/or static electricity. Empty only into inert or non-flammable atmosphere.
Emptying contents into a non-inert atmosphere where flammable vapors may be
present could cause a flash fire or explosion due to electrostatic discharge.
Containers
of this material may be hazardous when empty since they retain product residues
(dust, solids); observe all warnings and precautions listed for the product.
8.
Exposure Controls/Personal Protection
Airborne
Exposure Limits:-
OSHA Permissible Exposure Limit (PEL):
15
mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts.
-
ACGIH Threshold Limit Value (TLV):
10
mg/m3 total dust containing no asbestos and < 1% crystalline silica for
Particulates Not Otherwise Classified (PNOC). <BR> Ventilation System:A
system of local and/or general exhaust is recommended to keep employee exposures
below the Airborne Exposure Limits. Local exhaust ventilation is generally
preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the
ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most
recent edition, for details.
Personal
Respirators (NIOSH Approved):If
the exposure limit is exceeded, a half-face dust/mist respirator may be worn for
up to ten times the exposure limit or the maximum use concentration specified by
the appropriate regulatory agency or respirator supplier, whichever is lowest. A
full-face piece dust/mist respirator may be worn up to 50 times the exposure
limit, or the maximum use concentration specified by the appropriate regulatory
agency, or respirator supplier, whichever is lowest. For emergencies or
instances where the exposure levels are not known, use a full-facepiece
positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators
do not protect workers in oxygen-deficient atmospheres.
Skin
Protection:Wear
impervious protective clothing, including boots, gloves, lab coat, apron or
coveralls, as appropriate, to
prevent
skin contact.
Eye
Protection:Use
chemical safety goggles. Maintain eye wash fountain and quick-drench facilities
in work area.
9.
Physical and Chemical Properties
Appearance:
Transparent,
colorless crystals.
Odor:
Mousy odor.
Solubility:
1 g/500 mg
water; decomposes in hot water.
Density:
1.16
pH:
No information
found.
%
Volatiles by volume @ 21C (70F): 0
Boiling
Point: 221C
(430F)
Melting
Point: 82C
(180F)
Vapor
Density (Air=1): No
information found.
Vapor
Pressure (mm Hg): 1
@ 65C (149F)
Evaporation
Rate (BuAc=1): No
information found.
10.
Stability and Reactivity
Stability:
Stable under
ordinary conditions of use and storage.
Hazardous
Decomposition Products: Burning
may produce carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous
Polymerization: Will
not occur.
Incompatibilities:
Strong
oxidizers.
Conditions
to Avoid: Heat,
flame, ignition sources, incompatibles, light, and air.
11.
Toxicological Information
Oral
rat LD50: 7000 mg/kg; investigated as a tumorigen, mutagen, reproductive
effector. Cancer status: IARC
Category
2B.
--------\Cancer
Lists\------------------------------------------------------
---NTP
Carcinogen---
Ingredient
Known Anticipated IARC Category
------------------------------------
----- ----------- -------------
Acetamide
(60-35-5) No No 2B
12.
Ecological Information
Environmental
Fate: When
released into the soil, this material may biodegrade to a moderate extent. When
released into the soil, this material is expected to leach into groundwater.
When released into water, this material may biodegrade to a
moderate extent. When released into water, this material is not expected
to evaporate significantly. This material is
not expected to significantly bioaccumulate. When released into the air,
this material is expected to exist in the aerosol phase with a short half-life.
When released into the air, this material is expected to be readily removed from
the atmosphere by dry and wet
deposition.
Environmental
Toxicity: No
information found.
13.
Disposal Considerations
Whatever
cannot be saved for recovery or recycling should be managed in an appropriate
and approved waste
disposal
facility. Processing, use or contamination of this product may change the waste
management options.
State
and local disposal regulations may differ from federal disposal regulations.
Dispose of container and unused contents in accordance with federal, state and
local requirements.
14.
Transport Information
Not
regulated.
15.
Regulatory Information
--------\Chemical
Inventory Status - Part 1\---------------------------------
Ingredient
TSCA EC Japan Australia
-----------------------------------------------
---- --- ----- ---------
Acetamide
(60-35-5) Yes Yes Yes Yes
--------\Chemical
Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient
Korea DSL NDSL Phil.
-----------------------------------------------
----- --- ---- -----
Acetamide
(60-35-5) Yes Yes No Yes
--------\Federal,
State & International Regulations - Part 1\----------------
-SARA
302- ------SARA 313------
Ingredient
RQ TPQ List Chemical Catg.
-----------------------------------------
--- ----- ---- --------------
Acetamide
(60-35-5) No No Yes No
--------\Federal,
State & International Regulations - Part 2\----------------
-RCRA-
-TSCAIngredient
CERCLA
261.33 8(d)
-----------------------------------------
------ ------ ------
Acetamide
(60-35-5) 100 No No
Chemical
Weapons Convention: No TSCA 12(b): No CDTA: No
SARA
311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No
Reactivity:
No (Pure / Solid)
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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