NILE CHEMICALS
Synonyms: Diphenol; 1,1'biphenyl; phenylbenzene
CAS No.: 92-52-4
Molecular Weight: 154.21
Chemical Formula: C12H10
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Potential Health Effects
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Inhalation: Inhalation of dust or vapors can irritate the mucous
membranes and respiratory tract. Other symptoms may parallel those from
ingestion exposure.
Ingestion: Exerts toxic effects on the central nervous system and liver.
Symptoms may include headache, diffuse gastro-intestinal pain, nausea, numbness,
body aches, and general fatigue.
Skin Contact: May cause irritation. May be absorbed through the skin with
symptoms paralleling those from ingestion exposure. May cause allergic reaction
in sensitive individuals.
Eye Contact: Vapors and dust cause eye irritation.
Chronic Exposure: Chronic exposure may cause peripheral nerve damage and
liver injury.
Aggravation of Pre-existing Conditions: No information found.
Inhalation:Remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion:Induce vomiting immediately as directed by medical personnel.
Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact:Immediately flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Get medical
attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:Immediately flush eyes with plenty of water for at least 15
minutes, lifting lower and upper eyelids occasionally. Get medical attention
immediately.
Fire:Flash point: 113C (235F) CC
Autoignition temperature: 540C (1004F)
Flammable limits in air % by volume:
lel: 0.6; uel: 5.8
Explosion:Above the flash point, explosive vapor-air mixtures may be
formed. Fine dust dispersed in air in sufficient concentrations, and in the
presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media:Water spray, dry chemical, alcohol foam, or
carbon dioxide. Water or foam may cause frothing.
Special Information:In the event of a fire, wear full protective clothing
and NIOSH-approved self-contained breathing apparatus with full facepiece
operated in the pressure demand or other positive pressure mode.
Remove all sources of ignition. Ventilate area of leak or
spill. Wear appropriate personal protective equipment as specified in Section 8.
Spills: Clean up spills in a manner that does not disperse dust into the air.
Use non-sparking tools and equipment. Reduce airborne dust and prevent
scattering by moistening with water. Pick up spill for recovery or disposal and
place in a closed container. US Regulations (CERCLA) require reporting spills
and releases to soil, water and air in excess of reportable quantities.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
0.2 ppm (TWA).
-ACGIH Threshold Limit Value (TLV):
0.2 ppm (TWA)
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee
exposures below the Airborne Exposure Limits. Local exhaust ventilation is
generally preferred because it can control the emissions of the contaminant at
its source, preventing dispersion of it into the general work area. Please refer
to the ACGIH document, Industrial Ventilation, A Manual of Recommended
Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, a
half-face respirator with an organic vapor cartridge and particulate filter
(NIOSH type N95 or better filter) may be worn for up to ten times the exposure
limit or the maximum use concentration specified by the appropriate regulatory
agency or respirator supplier, whichever is lowest. A full-face piece respirator
with an organic vapor cartridge and particulate filter (NIOSH N 100 filter) may
be worn up to 50 times the exposure limit, or the maximum use concentration
specified by the appropriate regulatory agency or respirator supplier, whichever
is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.)
are present, use a NIOSH type R or P particulate filter. For emergencies or
instances where the exposure levels are not known, use a full-face piece
positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators
do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or
coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing
of solutions is possible. Maintain eye wash fountain and quick-drench facilities
in work area.
Appearance: White crystals.
Odor: Pleasant, peculiar odor.
Solubility: Insoluble in water.
Specific Gravity: 1.041
pH: No information found.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 254 - 255C (489 - 491F)
Melting Point: 69 - 70C (156 - 158F)
Vapor Density (Air=1): 5.31
Vapor Pressure (mm Hg): 0.005 @ 20.4C (68F)
Evaporation Rate (BuAc=1): No information found.
Stability: Stable under ordinary conditions of use
and storage.
Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may
form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Conditions to Avoid: Heat, flame, ignition sources, dusting and
incompatibles.
Toxicological Data:
Oral rat LD50 2400 mg/kg; Skin rabbit LD50: > 5010 mg/kg; Irritation (std
Draize) rabbit: eye = 100 mg, mild. Investigated as a tumorigen and mutagen.
Carcinogenicity:
EPA / IRIS classification: Group D1 - Not classifiable as a human carcinogen.
Environmental Fate: No information found.
Environmental Toxicity: No information found.
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
International (Water, I.M.O.)
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Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.
(DIPHENYL)
Hazard Class: 9
UN/NA: UN3077
Packing Group: III
Information reported for product/size: 1KG
International (Air, I.C.A.O.)
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Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.
(DIPHENYL)
Hazard Class: 9
UN/NA: UN3077
Packing Group: III
Information reported for product/size: 1KG
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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