NILE CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Bromoform
CAS#:
75-25-2
Synonym:
Tribromomethane
Chemical
Name: Methyl tribromide
Chemical
Formula: CHBr3
Section
2: Composition and Information on Ingredients Composition:
Name
CAS # % by Weight
Bromoform
75-25-2 100
Toxicological
Data on Ingredients: Bromoform:
ORAL (LD50): Acute: 933 mg/kg [Rat.]. 1072 mg/kg [Mouse].
Section
3: Hazards Identification
Potential
Acute Health Effects: Hazardous
in case of skin contact (irritant, permeator), of eye contact (irritant), of
ingestion, of inhalation.
Potential
Chronic Health Effects:
CARCINOGENIC
EFFECTS: Classified A3 (Proven for animal.) by ACGIH. MUTAGENIC EFFECTS: Not
available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available. The substance is toxic to kidneys, the nervous system, liver, upper
respiratory tract. Repeated or prolonged exposure to the substance can produce
target
organs
damage.
Section
4: First Aid Measures Eye Contact:
Check
for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Cold water may be used. WARM water
MUST be used. Get medical attention.
Skin
Contact: In case of
contact, immediately flush skin with plenty of water. Cover the irritated skin
with an emollient. Remove contaminated clothing and shoes. Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious
Skin Contact: Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek immediate medical attention.
Inhalation:
If inhaled, remove to
fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Serious
Inhalation: Evacuate the
victim to a safe area as soon as possible. Loosen tight clothing such as a
collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If
the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting
unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. If large quantities of this material are swallowed, call
a physician immediately. Loosen tight clothing such as a collar, tie, belt or
waistband.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: Non-flammable.
Auto-Ignition
Temperature: Not
applicable.
Flash
Points: Not applicable.
Flammable
Limits: Not applicable.
Products
of Combustion: Not
available.
Fire
Hazards in Presence of Various Substances: Not
applicable.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions: Not
applicable.
Special
Remarks on Fire Hazards: When
heated to decomposition it emits highly toxic fumes.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill: Absorb with an
inert material and put the spilled material in an appropriate waste disposal.
Large
Spill: Absorb with an
inert material and put the spilled material in an appropriate waste disposal. Be
careful that the product is not present at a concentration level above TLV.
Check TLV on the MSDS and with local authorities.
Section
7: Handling and Storage Precautions:
Keep
locked up.. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable
respiratory equipment. If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes. Keep away from
incompatibles such as oxidizing agents, metals, alkalis.
Storage:
Keep container tightly
closed. Keep container in a cool, well-ventilated area.
Section
8: Exposure Controls/Personal Protection Engineering
Controls:
Provide
exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapors below their respective threshold limit value.
Personal
Protection: Splash
goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.
Personal
Protection in Case of a Large Spill:
Splash
goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits:
TWA:
0.5 from ACGIH (TLV) [United States] [1996] SKIN TWA: 5.2 from ACGIH (TLV)
[United States] [1996] SKIN Consult
local
authorities for acceptable exposure limits.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Liquid.
(Liquid.)
Odor:
Chloroform.
Taste:
Not available.
Molecular
Weight: 252.77 g/mole
Color:
Colorless.
pH
(1% soln/water): 7
[Neutral.]
Boiling
Point: 149.5°C (301.1°F)
Melting
Point: 8.3 (46.9°F)
Critical
Temperature: Not
available.
Specific
Gravity: 2.89 (Water = 1)
Vapor
Pressure: 0.7 kPa (@ 20°C)
Vapor
Density: 8.7(Air = 1)
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: See solubility
in water, methanol, diethyl ether.
Solubility:
Partially
soluble in methanol, diethyl ether. Very slightly soluble in cold water, hot
water.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Not
available.
Incompatibility
with various substances: Reactive
with oxidizing agents, metals, alkalis.
Corrosivity:
Non-corrosive in presence
of glass.
Special
Remarks on Reactivity: Sensitive
to light.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
Will not occur.
Section
11: Toxicological Information
Routes
of Entry: Dermal contact.
Eye contact. Inhalation. Ingestion.
Toxicity
to Animals: Acute oral
toxicity (LD50): 933 mg/kg [Rat.].
Chronic
Effects on Humans:
CARCINOGENIC
EFFECTS: Classified A3 (Proven for animal.) by ACGIH. Causes damage to the
following organs: kidneys,
the
nervous system, liver, upper respiratory tract.
Other
Toxic Effects on Humans: Hazardous
in case of skin contact (irritant, permeator), of ingestion, of inhalation.
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Narcotic
effect; may cause nervous system disturbances.
Special
Remarks on other Toxic Effects on Humans: Material
is irritating to mucous membranes and upper respiratory tract.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation: Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are as toxic as the original product.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Section
14: Transport Information
DOT
Classification: CLASS 6.1:
Poisonous material.
Identification:
: Bromoform UNNA: UN2515
PG: III
Special
Provisions for Transport: Marine
Pollutant
Section
15: Other Regulatory Information
Federal
and State Regulations:
California
prop. 65: This product contains the following ingredients for which the State of
California has found to cause cancer, birth defects or other reproductive harm,
which would require a warning under the statute: Bromoform California prop.
65:This product contains the following ingredients for which the State of
California has found to cause cancer which would
require a warning under the statute: Bromoform Pennsylvania RTK:
Bromoform Florida: Bromoform Minnesota: Bromoform
Massachusetts
RTK: Bromoform New Jersey: Bromoform TSCA 8(b) inventory: Bromoform SARA 313
toxic chemical notification and release reporting: Bromoform CERCLA: Hazardous
substances.: Bromoform
Other
Regulations: OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other
Classifications:
WHMIS
(Canada): CLASS D-1B:
Material causing immediate and serious toxic effects (TOXIC).
DSCL
(EEC): R22- Harmful if
swallowed. R36/38- Irritating to eyes and skin. R40- Possible risks of
irreversible effects.
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 0
Reactivity:
0
Personal
Protection: h
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
0
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is inadequate. Splash
goggles.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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