NILE CHEMICALS
Synonyms: Chromium (III) Oxide Green; Chromic Oxide;
Chrome Oxide Green
CAS No.: 1308-38-9
Molecular Weight: 151.99
Chemical Formula: Cr2O3
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Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 1 - Slight
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Blue (Health)
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Potential Health Effects
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Inhalation: Causes irritation to the respiratory tract. Symptoms may
include coughing, shortness of breath.
Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may
include nausea, vomiting and diarrhea.
Skin Contact: Causes irritation to skin. Symptoms include redness,
itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: Prolonged or repeated skin contact may produce severe
irritation or dermatitis.
Aggravation of Pre-existing Conditions: No information found.
Inhalation:Remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion:Induce vomiting immediately as directed by medical personnel.
Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact:Immediately flush skin with plenty of water for at least 15
minutes. Remove contaminated clothing and shoes. Get medical attention. Wash
clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:Immediately flush eyes with plenty of water for at least 15
minutes, lifting lower and upper eyelids occasionally. Get medical attention
immediately.
Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing
surrounding fire.
Special Information: In the event of a fire, wear full protective
clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.
Ventilate area of leak or spill. Wear appropriate personal
protective equipment as specified in Section 8.
Spills: Pick up and place in a suitable container for reclamation or disposal in
a method that does not generate dust. Do not sweep. Damp mop any residue.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Do not store on wooden floors. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
for Cr(III) compounds = 0.5mg/m3 (TWA)
-ACGIH Threshold Limit Value (TLV):
for Cr(III) compounds = 0.5 mg/m3 (TWA), A4 - Not classifiable as a human
carcinogen
Ventilation System: A system of local and/or general exhaust is
recommended to keep employee exposures below the Airborne Exposure Limits. Local
exhaust ventilation is generally preferred because it can control the emissions
of the contaminant at its source, preventing dispersion of it into the general
work area. Please refer to the ACGIH document, Industrial Ventilation, A
Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded
and engineering controls are not feasible, a half facepiece particulate
respirator (NIOSH type N95 or better filters) may be worn for up to ten times
the exposure limit or the maximum use concentration specified by the appropriate
regulatory agency or respirator supplier, whichever is lowest.. A full-face
piece particulate respirator (NIOSH type N100 filters) may be worn up to 50
times the exposure limit, or the maximum use concentration specified by the
appropriate regulatory agency, or respirator supplier, whichever is lowest. If
oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present,
use a NIOSH type R or P filter. For emergencies or instances where the exposure
levels are not known, use a full-facepiece positive-pressure, air-supplied
respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.
Skin Protection:Wear impervious protective clothing, including boots,
gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where
dusting or splashing of solutions is possible. Maintain eye wash fountain and
quick-drench facilities in work area.
Appearance: Light to dark green Crystalline solid.
Odor: Odorless.
Solubility: Negligible (< 0.1%)
Specific Gravity: 5.10
pH: No information found.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 4000C (7232F)
Melting Point: 2435C (4415F)
Vapor Density (Air=1): Not applicable.
Vapor Pressure (mm Hg): Not applicable.
Evaporation Rate (BuAc=1): No information found.
Stability: Stable under ordinary conditions of use
and storage.
Hazardous Decomposition Products: No information found.
Hazardous Polymerization: Will not occur.
Incompatibilities: Lithium, glycerol.
Conditions to Avoid: Dusting.
Environmental Fate: When released into the soil,
this material is not expected to biodegrade. This material is not expected to
significantly bio accumulate.
Environmental Toxicity: No information found.
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Not regulated.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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