NILE CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Naphthalene
CAS#:
91-20-3
Chemical
Formula: C10H8
Section
2: Composition and Information on Ingredients Composition:
Name
CAS #
% by Weight
Naphthalene
91-20-3
100
Section
3: Hazards Identification Potential Acute Health Effects:
Very
hazardous in case of ingestion. Hazardous in case of eye contact (irritant), of
inhalation. Slightly hazardous in case of skin contact (irritant, permeator).
Severe over-exposure can result in death.
Potential
Chronic Health Effects:
CARCINOGENIC
EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. MUTAGENIC EFFECTS:
Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY:
Classified Development toxin [POSSIBLE]. The substance is toxic to blood,
kidneys, the nervous system, the reproductive system, liver, mucous membranes,
gastrointestinal tract, upper respiratory tract, central nervous system (CNS).
Repeated or prolonged exposure to the substance can produce target organs
damage. Repeated exposure to an highly toxic material may produce general
deterioration of health by an
accumulation
in one or many human organs.
Section
4: First Aid Measures Eye Contact:
Check
for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an
eye ointment. Seek medical attention.
Skin
Contact: After
contact with skin, wash immediately with plenty of water. Gently and thoroughly
wash the contaminated skin with running water and non-abrasive soap. Be
particularly careful to clean folds, crevices, creases and groin. Cover the
irritated skin with an emollient. If irritation persists, seek medical
attention. Wash contaminated clothing before reusing.
Serious
Skin Contact: Not
available.
Inhalation:
Allow the victim to rest
in a well ventilated area. Seek immediate medical attention.
Serious
Inhalation: Evacuate the
victim to a safe area as soon as possible. Loosen tight clothing such as a
collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If
the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It
may be hazardous to the person providing aid to give mouth-to-mouth
resuscitation when the inhaled material is toxic, infectious or corrosive. Seek
immediate medical attention.
Ingestion:Do
not induce vomiting. Examine the lips and mouth to ascertain whether the tissues
are damaged, a possible indication that the toxic material was ingested; the
absence of such signs, however, is not conclusive. Loosen tight clothing such as
a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: Flammable.
Auto-Ignition
Temperature: 567°C
(1052.6°F)
Flash
Points: CLOSED CUP: 88°C
(190.4°F). OPEN CUP: 79°C (174.2°F).
Flammable
Limits: LOWER: 0.9% UPPER:
5.9%
Products
of Combustion: These
products are carbon oxides (CO, CO2).
Fire
Hazards in Presence of Various Substances: Not
available.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions:
Flammable
solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog.
Cool containing vessels with water jet in order to prevent pressure build-up,
autoignition or explosion.
Special
Remarks on Fire Hazards: Not
available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill: Use appropriate
tools to put the spilled solid in a convenient waste disposal container.
Large
Spill: Flammable solid.
Stop leak if without risk. Do not touch spilled material. Use water spray
curtain to divert vapor drift. Prevent entry into sewers, basements or confined
areas; dike if needed. Eliminate all ignition sources. Call for assistance on
disposal. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local
authorities.
Section
7: Handling and Storage Precautions:
Keep
locked up Keep away from heat. Keep away from sources of ignition. Ground all
equipment containing material. Do not ingest. Do not breathe dust. Avoid contact
with eyes Wear suitable protective clothing In case of insufficient ventilation,
wear suitable respiratory equipment If ingested, seek medical advice immediately
and show the container or the label. Keep away from incompatibles such as
oxidizing agents.
Storage:Flammable
materials should be stored in a separate safety storage cabinet or room. Keep
away from heat. Keep away from sources of ignition. Keep container tightly
closed. Keep in a cool, well-ventilated place. Ground all equipment containing
material. Keep container dry. Keep in a cool place.
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection:Splash goggles.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Gloves.
Personal
Protection in Case of a Large Spill:
Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits:Israel: TWA: 10
(ppm) TWA: 10 STEL: 15 (ppm) from ACGIH (TLV) [1995] TWA: 52 STEL: 79 (mg/m3)
from ACGIH [1995] Australia: STEL: 15 (ppm) Consult local authorities for
acceptable exposure limits.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
(Crystalline solid.)
Odor:
Aromatic.
Taste:
Not available.
Molecular
Weight: 128.19 g/mole
Color:
White.
pH
(1% soln/water): Not
available.
Boiling
Point: 218°C (424.4°F)
Melting
Point: 80.2°C (176.4°F)
Critical
Temperature: Not
available.
Specific
Gravity: 1.162 (Water = 1)
Vapor
Pressure: Not applicable.
Vapor
Density: 4.4 (Air = 1)
Volatility:
Not available.
Odor
Threshold: 0.038 ppm
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties:
Partially
dispersed in hot water, methanol, n-octanol. Very slightly dispersed in cold
water. See solubility in methanol, noctanol.
Solubility:
Partially
soluble in methanol, n-octanol. Very slightly soluble in cold water, hot water.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Not
available.
Incompatibility
with various substances: Highly
reactive with oxidizing agents.
Corrosivity:
Non-corrosive in presence
of glass.
Special
Remarks on Reactivity: Not
available.
Special
Remarks on Corrosivity: May
attack some forms of rubber and plastic
Polymerization:
No.
Section
11: Toxicological Information
Routes
of Entry: Absorbed through
skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity
to Animals:
WARNING:
THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute
oral toxicity (LD50): 490 mg/kg [Rat]. Acute dermal toxicity (LD50): 20001 mg/kg
[Rabbit]. Acute toxicity of the vapor (LC50): 170 ppm 4 hour(s) [Rat].
Chronic
Effects on Humans:
CARCINOGENIC
EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. DEVELOPMENTAL
TOXICITY: Classified Development toxin [POSSIBLE]. The substance is toxic to
blood, kidneys, the nervous system, the reproductive system, liver, mucous
membranes, gastrointestinal tract, upper respiratory tract, central nervous
system (CNS).
Other
Toxic Effects on Humans:
Very
hazardous in case of ingestion. Hazardous in case of inhalation. Slightly
hazardous in case of skin contact (irritant, permeator).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans: Not
available.
Section
12: Ecological Information
Ecotoxicity:
Ecotoxicity in water
(LC50): 305.2 ppm 96 hour(s) [Trout].
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Section
14: Transport Information
DOT
Classification: CLASS 4.1:
Flammable solid.
Identification:
: Naphthalene, refined :
UN1334 PG: III
Special
Provisions for Transport: Marine
Pollutant
Section
15: Other Regulatory Information
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 2
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
2
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is inadequate. Splash
goggles.
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