NILE
CHEMICALS
NILE
CHEMICALS
PHLOXINE
B
Section
1: Chemical Product and Company Identification
Product
Name: Phloxine B
CAS#:
18472-87-2
CI#:
45410
Synonym:
Acid Red 92; D & C Red
#28; Aizen Acid Phloxine PB; CI Acid Red 92; Cyanosin; Cyanosin B; Cyanosine;
Daiwa Red 45; Eosin Blue; EosineBlue;FoodDyeRedNo.104;Red104; PhloxineP;Phloxin
B.8
Chemical
Name: Fluorescein,
2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-, disodium salt
Chemical
Formula: C20-H2-O5-Br40Cl4-Na2
Section
2: Composition and Information on Ingredients Composition:
Name
CAS #
% by Weight
Phloxine
B
18472-87-2
100
Toxicological
Data on Ingredients: Phloxine
B: ORAL (LD50): Acute: 8400 mg/kg [Rat]. 310 mg/kg [Mouse].
Section
3: Hazards Identification
Potential
Acute Health Effects: Slightly
hazardous in case of skin contact (irritant, permeator), of eye contact
(irritant), of ingestion, of inhalation.
Potential
Chronic Health Effects:
CARCINOGENIC
EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS:
Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged
exposure is not known to aggravate medical condition.
Section
4: First Aid Measures Eye Contact:
Check
for and remove any contact lenses. In case of contact, immediately flush eyes
with plenty of water for at least 15 minutes. Get medical attention.
Skin
Contact:In case of
contact, immediately flush skin with plenty of water. Cover the irritated skin
with an emollient. Remove contaminated clothing and shoes. Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious
Skin Contact: Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek medical attention.
Inhalation:
If inhaled, remove to
fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Serious
Inhalation: Not available.
Ingestion:Do
NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a
collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: May be
combustible at high temperature.
Auto-Ignition
Temperature: Not
available.
Flash
Points: Not available.
Flammable
Limits: Not available.
Products
of Combustion: These
products are carbon oxides (CO, CO2), halogenated compounds. Some metallic
oxides.
Fire
Hazards in Presence of Various Substances:
Slightly
flammable to flammable in presence of heat. Non-flammable in presence of shocks.
Explosion
Hazards in Presence of Various Substances:
Slightly
explosive in presence of open flames and sparks. Non-explosive in presence of
shocks.
Fire
Fighting Media and Instructions:
SMALL
FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special
Remarks on Fire Hazards: As
with most organic solids, fire is possible at elevated temperatures
Special
Remarks on Explosion Hazards: Fine
dust dispersed in air in sufficient concentrations, and in the presences of an
ignition source is a potential dust explosion hazard.
Section
6: Accidental Release Measures Small Spill:
Use
appropriate tools to put the spilled solid in a convenient waste disposal
container. Finish cleaning by spreading water on the contaminated surface and
dispose of according to local and regional authority requirements.
Large
Spill:Use a shovel to put
the material into a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the
sanitary system.
Section
7: Handling and Storage Precautions:
Keep
away from heat. Keep away from sources of ignition. Do not ingest. Do not
breathe dust. Wear suitable protective clothing. If ingested, seek medical
advice immediately and show the container or the label. Avoid contact with skin
and eyes.
Storage:
Keep container tightly
closed. Keep container in a cool, well-ventilated area.
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection:Splash goggles.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Gloves.
Personal
Protection in Case of a Large Spill: Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
Odor:
Not available.
Taste:
Not available.
Molecular
Weight: 829.66 g/mole
Color:
Red to Brown.
pH
(1% soln/water): Not
available.
Boiling
Point: Not available.
Melting
Point: Not available.
Critical
Temperature: Not
available.
Specific
Gravity: Not available.
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: Not available.
Solubility:
Partially soluble in cold
water.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Excess
heat
Incompatibility
with various substances: Not
available.
Corrosivity:
Not available.
Special
Remarks on Reactivity: Not
available.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
Not available.
Section
11: Toxicological Information
Routes
of Entry: Inhalation.
Ingestion.
Toxicity
to Animals: Acute oral
toxicity (LD50): 310 mg/kg [Mouse].
Chronic
Effects on Humans: Not
available.
Other
Toxic Effects on Humans: Slightly
hazardous in case of skin contact (irritant, permeator), of ingestion, of
inhalation.
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans:
May
cause adverse reproductive effects and birth defects (teratogenic) based on
animal test data. May affect genetic material (mutagenic). May cause cancer
based on animal test data.
Special
Remarks on other Toxic Effects on Humans:
Acute
Potential Health Effects: Skin: May cause irritation with redness and pain. May
be absorbed through the skin with possible systemic effects. Eyes: May cause
irritation, redness, and pain. Inhalation: May cause respiratory tract
irritation with coughing, sore throat, labored breathing, and chest pain.
Ingestion: May cause gastrointestinal tract irritation with nausea, vomiting,
and diarrhea. No other information found. Compound should be handled as a
potential health hazard.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic than the product itself.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Waste
must be disposed of in accordance with federal, state and local environmental
control regulations.
Section
14: Transport Information
DOT
Classification: Not a DOT
controlled material
Identification:
Not applicable.
Special
Provisions for Transport: Not
applicable.
Section
15: Other Regulatory Information
Federal
and State Regulations: TSCA
8(b) inventory: Phloxine B
Other
Regulations: OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
Other
Classifications:
WHMIS
(Canada): Not controlled
under WHMIS (Canada).
DSCL
(EEC): This product is not
classified according to the EU regulations. S24/25- Avoid contact with skin and
eyes.
HMIS
(U.S.A.):
Health
Hazard: 1
Fire
Hazard: 1
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
1
Flammability:
1
Reactivity:
0
Specific
hazard:
Protective
Equipment: Gloves. Lab
coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is inadequate. Safety
glasses.
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