NILE CHEMICALS

FERROUS AMMONIUM SULFATE

1. Product Identification

Synonyms: ferrous ammonium sulfate
CAS No.: 10045-89-3 Anhydrous; (7783-85-9 Hexahydrate)
Molecular Weight: 392.13
Chemical Formula: Fe(NH4)2(SO4)2 6H2O
Product Codes: 937

2. Composition/Information on Ingredients

   Ingredient                                CAS No         Percent        Hazardous                                  

  ---------------------------------------   ------------   ------------   ---------   

 Ferrous Ammonium Sulfate                  10045-89-3       90 - 100%       Yes                                                                    

3. Hazards Identification

Potential Health Effects
----------------------------------

Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.
Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. Low toxicity in small quantities but larger dosages may cause nausea, vomiting, diarrhea, and black stool. Pink urine discoloration is a strong indicator of iron poisoning. Liver damage, coma, and death from iron poisoning has been recorded.
Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of the substance.

4. First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard. Irritating and toxic ammonia gas may form in fires.
Explosion: Not considered to be an explosion hazard. Sealed containers may rupture when heated.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: 

7. Handling and Storage

Keep in a tightly closed light-resistant container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: -ACGIH Threshold Limit Value (TLV):
1 mg/m3 (TWA) soluble iron salt as Fe
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half facepiece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest.. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Pale blue-green crystals.
Odor: Odorless.
Solubility: 26.9 g/100cc water @ 20C (68F)
Specific Gravity: 1.86
pH: No information found.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not applicable.
Melting Point: 100 - 110C (212 - 230F)
Vapor Density (Air=1): > 1.0
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Slowly oxidizes in moist air.
Hazardous Decomposition Products: May emit ammonia, oxides of sulfur, oxides of nitrogen, and oxides of carbon.
Hazardous Polymerization: Will not occur.
Incompatibilities: Sulfuric acid
Conditions to Avoid: Heat, light, moisture.

11. Toxicological Information

Oral rat LD50: 3250 mg/kg

  --------\Cancer Lists\------------------------------------------------------                                         ---NTP Carcinogen---

  Ingredient                             Known    Anticipated    IARC Category

  ------------------------------------   -----    -----------    -------------

  Ferrous Ammonium Sulfate                No          No            None

  (10045-89-3)

12. Ecological Information

Environmental Fate: No information found.
Environmental Toxicity: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

 Ferrous Ammonium Sulfate (10045-89-3)      1000       No         No   

16. Other Information

Nile Chemicals provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. NILE CHEMICALS MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE CHEMICALS WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.

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